H-1 NMR spectra of Ph(2)SbX, PhSbX(2), and Ph(3)SbX(2) (X=Cl,Br,I); Sb-121 Mossbauer spectra of PhSbX(2) and crystal structure of Ph(2)SbI

被引：10

作者：

Alonzo, G

Breunig, HJ

Denker, M

Ebert, KH

Offermann, W

机构：

[1] UNIV BREMEN,FACHBEREICH 2,D-28334 BREMEN,GERMANY

[2] UNIV PALERMO,DIPARTIMENTO CHIM INORGAN,I-90123 PALERMO,ITALY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 522卷 / 02期

关键词：

antimony; H-1 NMR spectra; crystal structure; Sb-121 Mossbauer spectra; group; 15; phenyl;

D O I：

10.1016/0022-328X(96)06286-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

H-1 NMR spectroscopic data of Ph(2)SbX, PhSbX(2), and Ph(3)SbX(2) (X=Cl, Br, I) have been determined by iterative simulation. Sb-121 Mossbauer spectra of PhSbX(2) (X=Cl, Br, I) have been measured. The synthesis of Ph(2)SbCl is achieved by reaction of Ph(2)SbCl with NaI in ethanol. The crystal structure of Ph(2)SbI consists of molecules with pyramidal C2SbI units.

引用

页码：237 / 240

页数：4

共 16 条

[1] SB-121 MOSSBAUER-SPECTRA OF ORGANOANTIMONY DERIVATIVES CONTAINING SB-SB BONDS
ALONZO, G
BERTAZZI, N
BREUNIG, HJ
EBERT, KH
[J]. HYPERFINE INTERACTIONS, 1994, 90 (1-4): : 505 - 508
[2] PREPARATION OF TRIPHENYLARSINE- AND TRIPHENYLSTIBINE-DICHLORIDES
BANISTER, AJ
MOORE, LF
[J]. JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1968, (05): : 1137 - &
[3] Becker G., 1992, UNKONVENTIONELLE WEC
[4] BONE SP, 1979, J CHEM SOC DA, P1431
[5] Hollemann A. F., 1995, LEHRBUCH ANORGANISCH, DOI DOI 10.1007/s11869-008-0001-3
[6] Michaelis A., 1886, LIEBIGS ANN CHEM, V233, P39
[7] PREPARATION AND CRYSTAL-STRUCTURES OF 5 ORGANOANTIMONY HALIDES - (P-TOLYL)ANTIMONY(III) DICHLORIDE AND DIBROMIDE, DIPHENYLANTIMONY(III) BROMIDE, (BIPHENYL-2,2'-DIYL)ANTIMONY(III) CHLORIDE AND BIS-(2'-CHLOROBIPHENYL-2-YL)ANTIMONY(V) TRICHLORIDE
MILLINGTON, PL
SOWERBY, DB
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 480 (1-2) : 227 - 234
[8] ELEMENT-ELEMENT BONDS .7. INTERMOLECULAR INTERACTIONS IN DIHALOGEN(PHENYL)STIBANES
MUNDT, O
BECKER, G
STADELMANN, H
THURN, H
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1992, 617 (11): : 59 - 71
[9] THE PREPARATION OF PHENYL SUBSTITUTED ANTIMONY(III) AND ANTIMONY(V) CHLORIDES AND BROMIDES
NUNN, M
SOWERBY, DB
WESOLEK, DM
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 251 (03) : C45 - C46
[10] SEVERENGIZ T, 1980, CHEM ZTG, V104, P202

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