Highly efficient blue-emitting iridium(III) carbene complexes and phosphorescent OLEDs

被引：359

作者：

Chang, Chiung-Fang ^{[1
]}

Cheng, Yi-Ming ^{[1
]}

Chi, Yun ^{[1
]}

Chiu, Yuan-Chieh ^{[1
]}

Lin, Chao-Chen ^{[2
]}

Lee, Gene-Hsiang ^{[2
]}

Chou, Pi-Tai ^{[2
]}

Chen, Chung-Chia ^{[3
,4
]}

Chang, Chih-Hao ^{[3
,4
]}

Wu, Chung-Chih ^{[3
,4
]}

机构：

[1] Natl Tsing Hua Univ, Dept Chem, Hsinchu 300, Taiwan

[2] Natl Taiwan Univ, Dept Chem, Taipei 106, Taiwan

[3] Natl Taiwan Univ, Dept Elect Engn, Grad Inst Photon & Optoelect, Taipei 106, Taiwan

[4] Natl Taiwan Univ, Grad Inst Elect Engn, Taipei 106, Taiwan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 24期

关键词：

carbene ligands; density functional calculations; iridium; luminescence; N ligands;

D O I：

10.1002/anie.200800748

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Bright & blue: A strategy for reducing metal-chelate internal strain enables the preparation of blue emitting iridium(III) carbene complexes (see picture; Ir red, N light blue, F green). The phosphorescent OLED fabricated from one of these complexes shows remarkable CIE coordinates of (0.16, 0.13) and peak efficiencies of 6.0% photons per electron, 6.3 cdA -1, and 4.0 lmW-1. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4542 / 4545

页数：4

共 46 条

[1] SYNTHETIC CONTROL OF EXCITED-STATE PROPERTIES - TRIS-CHELATE COMPLEXES CONTAINING THE LIGANDS 2,2'-BIPYRAZINE, 2,2'-BIPYRIDINE, AND 2,2'-BIPYRIMIDINE [J].

ALLEN, GH ;

WHITE, RP ;

RILLEMA, DP ;

MEYER, TJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (09) :2613-2620

[2]

[Anonymous], 2007, ANGEW CHEM

[3] Influence of substituents on the energy and nature of the lowest excited states of heteroleptic phosphorescent Ir(III) complexes: A joint theoretical and experimental study [J].

Avilov, Igor ;

Minoofar, Payam ;

Cornil, Jerome ;

De Cola, Luisa .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (26) :8247-8258

[4] Neutral and cationic fluorinated N-heterocyclic carbene complexes of rhodium and iridium [J].

Burling, Suzanne ;

Mahon, Mary F. ;

Reade, Steven P. ;

Whittlesey, Michael K. .

ORGANOMETALLICS, 2006, 25 (15) :3761-3767

[5] Preparation of Au(I), Ag(I), and Pd(II) N-heterocyclic carbene complexes utilizing a methylpyridyl-substituted NHC ligand. Formation of a luminescent coordination polymer [J].

Catalano, Vincent J. ;

Etogo, Anthony O. .

INORGANIC CHEMISTRY, 2007, 46 (14) :5608-5615

[6] Color tuning associated with heteroleptic cyclometalated Ir(III) complexes: influence of the ancillary ligand [J].

Chang, Chau-Jiun ;

Yang, Cheng-Han ;

Chen, Kellen ;

Chi, Yun ;

Shu, Ching-Fong ;

Ho, Mei-Lin ;

Yeh, Yu-Shan ;

Chou, Pi-Tai .

DALTON TRANSACTIONS, 2007, (19) :1881-1890

[7] Novel, highly efficient blue-emitting heteroleptic iridium(III) complexes based on fluorinated 1,3,4-oxadiazole: tuning to blue by dithiolate ancillary ligands [J].

Chen, Lianqing ;

You, Han ;

Yang, Chuluo ;

Ma, Dongge ;

Qin, Jingui .

CHEMICAL COMMUNICATIONS, 2007, (13) :1352-1354

[8] Contemporary progresses on neutral, highly emissive Os(II) and Ru(II) complexes [J].

Chi, Yun ;

Chou, Pi-Tai .

CHEMICAL SOCIETY REVIEWS, 2007, 36 (09) :1421-1431

[9] Structural variations in novel silver(I) complexes with bitopic pyrazole/N-heterocyclic carbene ligands [J].

Chiu, PL ;

Chen, CY ;

Lee, CC ;

Hsieh, MH ;

Chuang, CH ;

Lee, HM .

INORGANIC CHEMISTRY, 2006, 45 (06) :2520-2530

[10] Phosphorescent dyes for organic light-emitting diodes [J].

Chou, Pi-Tai ;

Chi, Yun .

CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (02) :380-395

← 1 2 3 4 5 →