Structural chemistry, magnetism and thermodynamic properties of R2Pd2In

被引:66
作者
Giovannini, M
Michor, H
Bauer, E
Hilscher, G
Rogl, P
Ferro, R
机构
[1] Vienna Tech Univ, Inst Expt Phys, A-1040 Vienna, Austria
[2] Univ Genoa, Dipartimento Chim & Chim Ind, I-16132 Genoa, Italy
[3] Univ Vienna, Inst Phys Chem, A-1090 Vienna, Austria
基金
奥地利科学基金会;
关键词
rare-earth palladium indides; ternary rare earth intermetallics; magnetic properties; resistivity; specific heat;
D O I
10.1016/S0925-8388(98)00723-3
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We report on magnetisation, resistivity and specific heat measurements of R2Pd2In compounds synthesised with the nominal composition R40Pd41In19 (R=La, Ce, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu and Y), Magnetic and thermodynamic measurements reveal antiferromagnetic order below 32 K for this series except for Y, La, Yb and Lu. An appreciably wide homogeneity range is found for Ce2Pd2+xIn1-x where ferro- or antiferromagnetic order or both occur with typical features of a Kondo lattice. Yb2Pd2In exhibits intermediate valent behaviour and no magnetic order could be detected down to 0.3 K. (C) 1998 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:26 / 38
页数:13
相关论文
共 17 条
[1]  
Carvajal J. R., 1990, SAT M POWD DIFFR 15, P127
[2]  
CHEVALIER B, 1997, 12 INT C SOL STAT CH
[3]   THEORY OF RESISTANCE OF RARE EARTH METALS [J].
ELLIOTT, RJ ;
WEDGWOOD, FA .
PROCEEDINGS OF THE PHYSICAL SOCIETY OF LONDON, 1963, 81 (523) :846-&
[4]  
GIOVANNINI M, 1998, IN PRESS
[5]  
GODART C, COMMUNICATION
[6]   MAGNETIC-PROPERTIES OF SEVERAL CE(2)T(2)M PHASES WITH T=NI, PD AND M=IN, SN, PB [J].
GORDON, RA ;
IJIRI, Y ;
SPENCER, CM ;
DISALVO, FJ .
JOURNAL OF ALLOYS AND COMPOUNDS, 1995, 224 (01) :101-107
[7]   Magnetic behavior of new Ce-Pd-Sn ternary compounds [J].
Gordon, RA ;
DiSalvo, FJ .
JOURNAL OF ALLOYS AND COMPOUNDS, 1996, 238 (1-2) :57-64
[8]  
Grimvall G., 1981, ELECT PHONON INTERAC
[9]   ON NEW MO2FEB2-TYPE REPRESENTATIVES M(2)PD(2)IN [J].
HULLIGER, F ;
XUE, BZ .
JOURNAL OF ALLOYS AND COMPOUNDS, 1994, 215 (1-2) :267-270
[10]   Field and pressure studies of Ce2Pd2In [J].
Kaczorowski, D ;
Giovannini, M ;
Hauser, R ;
Michor, H ;
Bauer, E ;
Hilscher, G .
CZECHOSLOVAK JOURNAL OF PHYSICS, 1996, 46 :2063-2064