Toward the rational design of supramolecular coordination polymers. The effect of solvent and substituent changes on the structure of self-assembled metal-organometallic networks

被引：45

作者：

Oh, M ^{[1
]}

Carpenter, GB ^{[1
]}

Sweigart, DA ^{[1
]}

机构：

[1] Brown Univ, Dept Chem, Providence, RI 02912 USA

来源：

ORGANOMETALLICS | 2003年 / 22卷 / 12期

关键词：

D O I：

10.1021/om0302600

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Self-assembly of the pi-complex (eta(4)-benzoquinone)Mn(CO)(3)(-) (QMTC) with metal ions [Mn(11), Co(11), Zn(II)] generates neutral metal-organometallic coordination networks (MOMNs). The network architecture can be controlled by (1) a solvent-induced change in coordination geometry at the metal nodes and (2) the introduction of substituents on the benzoquinone ring.

引用

页码：2364 / 2366

页数：3

共 36 条

[1] Supramolecular isomerism in coordination compounds: Nanoscale molecular hexagons and chains [J].