A new model for the substitution patterns in the polymer chain of polysaccharide derivatives

被引：31

作者：

Mischnick, P

Hennig, C

机构：

[1] Braunschweig Univ TEchnol, Inst Food Chem, D-38106 Braunschweig, Germany

[2] Univ Hamburg, Ctr Model Bldg & Simulat, Fac Math, D-20146 Hamburg, Germany

来源：

BIOMACROMOLECULES | 2001年 / 2卷 / 01期

关键词：

D O I：

10.1021/bm000093c

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

A new mathematical model is presented for the analysis of the substituent distribution in the polymer chain of polysaccharide derivatives. For the first time, the influence of substitution on the reactivity of neighbored monomer units is taken into account. The model was applied to various cellulose and amylose ethers and esters and excellently fits the experimental data.

引用

页码：180 / 184

页数：5

共 22 条

[1] SUBSTITUENT DISTRIBUTION ALONG THE CELLULOSE BACKBONE IN O-METHYLCELLULOSES USING GC AND FAB-MS FOR MONOMER AND OLIGOMER ANALYSIS [J].