Stereoselective phenyl migration from silicon to carbon

被引：23

作者：

Studer, A ^{[1
]}

Bossart, M ^{[1
]}

Steen, H ^{[1
]}

机构：

[1] ETH Zurich, Organ Chem Lab, CH-8092 Zurich, Switzerland

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 48期

关键词：

D O I：

10.1016/S0040-4039(98)02045-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In the present letter, the first stereoselective radical 1,5 phenyl transfer from silicon to carbon is reported. Diphenyl(trimethylsilyl)silyl ethers, the corresponding germylated and stannylated derivatives, and also some silyl ethers derived from commercially available silicon protecting groups were tested in this ipso substitution reaction. Diastereoselectivities of up to 11:1 were obtained. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：8829 / 8832

页数：4

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