CH3OH adsorption on clean and Cu-predeposited α-Fe2O3(0001) surfaces

被引：13

作者：

Guo, QL

McBreen, PH

Moller, PJ

机构：

[1] Univ Copenhagen, Dept Chem, DK-2100 Copenhagen, Denmark

[2] Univ Laval, Dept Chem, Quebec City, PQ G1K 7P4, Canada

来源：

SURFACE SCIENCE | 1999年 / 423卷 / 01期

关键词：

alcohols; catalysis; compound formation; copper; electron energy loss spectroscopy; iron oxide; low index single crystal surfaces; vibrations of adsorbed molecules;

D O I：

10.1016/S0039-6028(98)00883-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The adsorption of methanol on clean and ultra-thin layer copper-deposited alpha-Fe2O3(0001) surfaces was studied using HREELS. Intact molecular adsorption is found for both types of surface. HREELS measurements made following anneals to various temperatures indicate that monolayer methanol desorbs from alpha-Fe2O3(0001) between 140 and 180 K, No evidence was found for the formation of species such as formate on the composite Cu/alpha-Fe2O3(0001) surface. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

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页码：19 / 23

页数：5

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