"Clicking" Polymers or Just Efficient Linking: What Is the Difference?

被引：535

作者：

Barner-Kowollik, Christopher ^{[1
]}

Du Prez, Filip E. ^{[2
]}

Espeel, Pieter ^{[2
]}

Hawker, Craig J. ^{[3
]}

Junkers, Tanja ^{[4
]}

Schlaad, Helmut ^{[5
]}

Van Camp, Wim ^{[2
]}

机构：

[1] KIT, ITCP, Engesserstr 18, D-76128 Karlsruhe, Germany

[2] Univ Ghent, Polymer Chem Res Grp, Ghent, Belgium

[3] Univ Calif Santa Barbara, Mat Res Lab, Santa Barbara, CA 93106 USA

[4] Hasselt Univ, Inst Mat Res, IMO, Diepenbeek, Belgium

[5] Max Planck Inst Colloids & Interfaces, D-14424 Potsdam, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 01期

关键词：

click reactions; polymer chemistry; polymer conjugation; selectivity; CHEMISTRY;

D O I：

10.1002/anie.201003707

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The "click" trick: Many reactions are classified as click reactions even though some are limited to certain applications. Thus, there is danger that the term "click" will become meaningless over time and simply a synonym for "successful". To prevent this, the original click criteria are evaluated in this Essay specifically for the synthetic polymer field and a set of criteria are specified that distinguishes click from other efficient reactions. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：60 / 62

页数：3

共 18 条

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