Laser photolysis study on mechanism and efficiency of electron transfer between fullerenes (C60 and C70) and tetraselenafulvalenes

被引：11

作者：

Alam, MM

Ito, O ^{[1
]}

Sakurai, N

Moriyama, H

机构：

[1] Tohoku Univ, Inst Chem React Sci, Aoba Ku, Sendai, Miyagi 9808577, Japan

[2] Toho Univ, Dept Chem, Funabashi, Chiba 274, Japan

来源：

FULLERENE SCIENCE AND TECHNOLOGY | 1998年 / 6卷 / 06期

关键词：

D O I：

10.1080/10641229809350252

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Efficient electron-transfer reactions from three kind of tetraselenafulvalenes (TSeF's) to photoexcited triplet state of C-60 or C-70 in polar solvents have been confirmed by transient absorption spectroscopy observing the decay of C-3(60)*/C-3(70)* and rise of C-60(-.)/C-70(-.) Growth of single crystal seems to be stimulated by laser irradiation of the solution containing C-60 and bis(ethylenedithio)tetraselenafulvalene (BEDT-TSeF), in which C-60(-.) was effectively formed.

引用

页码：1007 / 1024

页数：18

共 40 条

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