Zeolite titanium beta: A selective and water resistant catalyst in Meerwein-Ponndorf-Verley-Oppenauer reactions

被引：54

作者：

vanderWaal, JC ^{[1
]}

Tan, KQ ^{[1
]}

vanBekkum, H ^{[1
]}

机构：

[1] TIANJIN RES INST CHEM IND,TIANJIN 300131,PEOPLES R CHINA

来源：

CATALYSIS LETTERS | 1996年 / 41卷 / 1-2期

关键词：

zeolite Ti-beta; Meervein-Ponndorf-Verley reduction; Oppenauer oxidation; transition-state selectivity; 4-t-butylcyclohexanone; 4-t-butylcyclohexanol; methylcyclohexanones;

D O I：

10.1007/BF00811714

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Aluminium-free zeolite titanium beta was found to be a selective and water stable catalyst in the Meerwein-Ponndorf-Verley reduction of alkylcyclohexanones and the Oppenauer oxidation of alkylcyclohexanol. 4-t-butyl- and 4-methylcyclohexanone were reduced with > 98% selectivity to the cis-alcohol. The high stereoselectivity is explained by transition-state selectivity.

引用

页码：63 / 67

页数：5

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