Modular assembly between biimidazole complexes and chloride anions.: Crystal structures of [Cu(biimidazole)2]Cl2 and [Zn(Cl)(biimidazole)2]Cl

被引：25

作者：

Atencio, R

Ramírez, K

Reyes, JA

González, T

Silva, P

机构：

[1] IVIC, Lab Sintesis & Caracterizac Nuevos Mat, Ctr Quim, Caracas 1020 A, Venezuela

[2] IVIC, Lab Fis Mat Condensada, Inst Venezolano Invest Cient, Caracas 1020 A, Venezuela

来源：

INORGANICA CHIMICA ACTA | 2005年 / 358卷 / 03期

关键词：

Cu-complexes; Zn-complexes; modular assembly; hydrogen bonding;

D O I：

10.1016/j.ica.2004.09.059

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The strong affinity of coordinated biimidazole for chloride ion via N-(HCl-)-Cl-... hydrogen bonding has been used as a strategy to build up two different modular assemblies between chloride and biimidazole-metal modules. The crystal structure of these two new metal-containing architectures, {[Cu(H(2)biim)(2)]Cl-2 (1) and [Zn(Cl)(H(2)biim)(2)]Cl (2)}, is reported. The EPR spectrum of 1 is also discussed. (C) 2004 Elsevier B.V. All rights reserved.

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页码：520 / 526

页数：7

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