共 37 条
A cationic three-coordinate iron(II) complex and the reaction of β-diketiminate with ethyl diazoacetate
被引:41
作者:

Gregory, EA
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机构:
Univ Rochester, Dept Chem, Rochester, NY 14627 USA Univ Rochester, Dept Chem, Rochester, NY 14627 USA

Lachicotte, RJ
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Univ Rochester, Dept Chem, Rochester, NY 14627 USA Univ Rochester, Dept Chem, Rochester, NY 14627 USA

Holland, PL
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Univ Rochester, Dept Chem, Rochester, NY 14627 USA Univ Rochester, Dept Chem, Rochester, NY 14627 USA
机构:
[1] Univ Rochester, Dept Chem, Rochester, NY 14627 USA
关键词:
D O I:
10.1021/om0489913
中图分类号:
O61 [无机化学];
学科分类号:
070301 ;
081704 ;
摘要:
We report the synthesis of a cationic iron(II) complex in which the iron atom is 3-coordinate in solution and in the solid state. The complex undergoes an unusual addition of ethyl diazoacetate, in which the diketiminate forms a bond to the terminal nitrogen of the diazo group. Coordination of the ester group to iron is proposed to activate the diazo group so that it is attacked by the nucleophilic diketiminate ligand.
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页码:1803 / 1805
页数:3
相关论文
共 37 条
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