Spectral features of the aggregation of TPPS4 in the presence of cation surfactant

被引：16

作者：

Huang, CZ ^{[1
]}

Li, YF ^{[1
]}

Huang, XH ^{[1
]}

Liu, SP ^{[1
]}

机构：

[1] SW Normal Univ, Inst Environm Chem, Chongqing 400715, Peoples R China

来源：

ACTA PHYSICO-CHIMICA SINICA | 1998年 / 14卷 / 08期

关键词：

cetyltrimethylammoniumbromide (CTMAB); meso-tetrakis(p-sulfonatophenyl)porphine (TPPS4); absorption spectrum; fluorescence spectrum; resonance light-scattering spectrum;

D O I：

10.3866/PKU.WHXB19980812

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This paper presents the spectroscopic features of the aggregation of meso- tetrakis(p-sulfonatophenyl)porphine (TPPS4) induced by cetyltrimethylammoniumbromide (CTMAB). Spectra studied involve absorption, fluorescence and resonance light-scattering. The results show that J-type aggregates of TPPS4 can be produced with two TPPS4 molecules being stacked in the structure of staggering card-deck when the concentration of CTMAB is lower than 1.0x10(-5) mol.L-1 The J-type aggregates of TPPS4 still exist with a hypsochromic Soret band when the concentration of CTMAB is in the range 1.0x10(-5) similar to 1.0x10(-4) mol.L-1. The J-type aggregates, however, disappear with the appearance of the D-2h absorption features of free base porphyrin if the concentration of CTMAB is higher than 1.0x10(-4) mol.L-1. Compared with the spectroscopic features of the Gee base porphyrin in water medium, the Soret band of the free base porphyrin in CTMAB medium is red-shifted.

引用

页码：731 / 736

页数：6

共 16 条

[1] Recognition by a solubilized receptor: Hydrogen bonding, solvophobic interactions, and solvent engineering inside micelles [J].

BonarLaw, RP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (50) :12397-12407

[2]

CHEN GZ, 1990, FLUORIMETRY, P93

[3] CHIRAL MICELLAR PORPHYRIN FIBERS WITH 2-AMINOGLYCOSAMIDE HEAD GROUPS [J].

FUHRHOP, JH ;

DEMOULIN, C ;

BOETTCHER, C ;

KONING, J ;

SIGGEL, U .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (11) :4159-4165

[4]

Guan Jingqu, 1994, Huanjing Kexue, V15, P81

[5]

HE JJ, 1997, ZHONGGUO KEXUE, V27, P930

[6]

Huang C Z., 1996, THESIS PEKING U

[7]

Huang CZ, 1997, CHEM J CHINESE U, V18, P525

[8] Determination of albumin and globulin at nanogram levels by a resonance light-scattering technique with alpha,beta,gamma,delta-tetrakis(4-sulfophenyl)porphine [J].

Huang, CZ ;

Zhu, JX ;

Li, KA ;

Tong, SY .

ANALYTICAL SCIENCES, 1997, 13 (02) :263-268

[9] Determination of nanograms of nucleic acids by their enhancement effect on the resonance light scattering of the cobalt(II)/4-[(5-chloro-2-pyridyl)azo]-1,3-diaminobenzene complex [J].

Huang, CZ ;

Li, KA ;

Tong, SY .

ANALYTICAL CHEMISTRY, 1997, 69 (03) :514-520

[10] Determination of nucleic acids by a resonance light-scattering technique with alpha,beta,gamma,delta-tetrakis[4-(trimothylammoniumyl)phenyl]porphine [J].

Huang, CZ ;

Li, KA ;

Tong, SY .

ANALYTICAL CHEMISTRY, 1996, 68 (13) :2259-2263

← 1 2 →