High-Yield Synthesis of a Hybrid 2,3,4,5-Tetracarba-1,6-nido-hexaborane(6) Cluster with an exo-Polyhedral Boracycle

被引：12

作者：

Braunschweig, Holger ^{[1
]}

Ghosh, Sundargopal ^{[2
]}

Kupfer, Thomas ^{[1
]}

Radacki, Krzysztof ^{[1
]}

Wahler, Johannes ^{[1
]}

机构：

[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

[2] Indian Inst Technol, Dept Chem, Madras 600036, Tamil Nadu, India

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2011年 / 17卷 / 15期

关键词：

borole; boron; nido-carborane; organoborane; reduction; BORON; CHEMISTRY; CARBORANE; REDUCTION; SYSTEMS; ANTIAROMATICITY; METALLABORANES; DIMERIZATION; RESONANCE; INSERTION;

D O I：

10.1002/chem.201100453

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Coupled cluster: An unprecedented 2,3,4,5-tetracarba-1,6-nido-hexaborane(6) cluster is accessible from a borole precursor in two steps involving a mild reduction process. The title compound consists of a perphenylated cluster framework, which is linked to an exo-polyhedral boracycle. This was confirmed by NMR spectroscopy and X-ray crystallography. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：4081 / 4084

页数：4

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