Mechanism of ruthenium-catalyzed hydrogen transfer reactions.: Evidence for a stepwise transfer of CH and NH hydrogens from an amine to a (cyclopentadienone) ruthenium complex

被引：48

作者：

Éll, AH ^{[1
]}

Johnson, JB ^{[1
]}

Bäckvall, JE ^{[1
]}

机构：

[1] Stockholm Univ, Arrhenius Lab, Dept Organ Chem, SE-10691 Stockholm, Sweden

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 14期

关键词：

D O I：

10.1039/b303258b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Kinetic deuterium isotope effects and racemization studies indicate that dehydrogenation of an amine by a (cyclopentadienone) ruthenium complex occurs via a slow beta-hydride elimination of coordinated amine followed by a proton transfer from nitrogen to carbonyl oxygen.

引用

页码：1652 / 1653

页数：2

共 26 条

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