Lithium Distribution in Aluminum-Free Cubic Li7La3Zr2O12

被引：230

作者：

Xie, Hui ^{[1
]}

Alonso, Jose A. ^{[2
]}

Li, Yutao ^{[3
]}

Fernandez-Diaz, Maria T. ^{[4
]}

Goodenough, John B. ^{[1
]}

机构：

[1] Univ Texas Austin, Mat Sci & Engn Program, Austin, TX 78712 USA

[2] CSIC, Inst Ciencia Mat Madrid, E-28049 Madrid, Spain

[3] Tsinghua Univ, State Key Lab New Ceram & Fine Proc, Dept Mat Sci & Engn, Beijing 100084, Peoples R China

[4] Inst Max Von Laue Paul Langevin, F-38042 Grenoble 9, France

来源：

CHEMISTRY OF MATERIALS | 2011年 / 23卷 / 16期

关键词：

lithium garnet; Li7La3Zr2O12; solid electrolyte; neutron diffraction; TRANSPORT-PROPERTIES; ION CONDUCTIVITY; GARNETS; PR; ND; LN;

D O I：

10.1021/cm201671k

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Li sites and occupancies are determined by neutron diffraction of cubic Al-free Li7La3Zr2O12. Maximum 7.5 Li per formula unit in the garnet formwork can be determined from the model, with half of the tetrahedral sites vacant and long-range ordered. © 2011 American Chemical Society.

引用

页码：3587 / 3589

页数：3

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