Synthesis and structure of a S4Si4 cage compound

被引：6

作者：

Ackerhans, C ^{[1
]}

Roesky, HW ^{[1
]}

Noltemeyer, M ^{[1
]}

机构：

[1] Univ Gottingen, Inst Anorgan Chem, D-37077 Gottingen, Germany

来源：

ORGANOMETALLICS | 2001年 / 20卷 / 07期

关键词：

D O I：

10.1021/om000899t

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of the tetraaminodisilane R2Si2-(NH2)(4) (R = CH(SiMe3)(2)) with liquid H2S at -70 degreesC resulted in the formation of a R4S4Si4 cage. The core of the molecule consists of four five-membered rings. Two disilane units are bridged cross over by four sulfur atoms. This is a new structural type in the group of silicon-sulfur ring and cluster compounds.

引用

页码：1282 / 1284

页数：3

共 25 条

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