A programmable molecular diode driven by charge-induced conformational changes

被引：53

作者：

Derosa, PA ^{[1
]}

Guda, S ^{[1
]}

Seminario, JM ^{[1
]}

机构：

[1] Univ S Carolina, Dept Elect Engn, Columbia, SC 29208 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 47期

关键词：

D O I：

10.1021/ja035071n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The 3-nitro-2-(3′-nitro-2′-ethynylpyridine)-5-thiopyridine molecule shows charge-induced conformational switching and a rectifying behavior with a charge-induced controllable switching. This device can be used as a memory operated with an external field interacting with one of the rings local dipole. Alternatively, the molecule can be used as a nano-actuator controlling the rotation of the ring by charging the molecule with a bias voltage. Copyright © 2003 American Chemical Society.

引用

页码：14240 / 14241

页数：2

共 23 条

[1] DENSITY-FUNCTIONAL THERMOCHEMISTRY .3. THE ROLE OF EXACT EXCHANGE [J].

BECKE, AD .

JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (07) :5648-5652

[2] A [2]catenane-based solid state electronically reconfigurable switch [J].

Collier, CP ;

Mattersteig, G ;

Wong, EW ;

Luo, Y ;

Beverly, K ;

Sampaio, J ;

Raymo, FM ;

Stoddart, JF ;

Heath, JR .

SCIENCE, 2000, 289 (5482) :1172-1175

[3] EFFECTIVE CORE POTENTIAL METHODS FOR THE LANTHANIDES [J].

CUNDARI, TR ;

STEVENS, WJ .

JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (07) :5555-5565

[4] Electron transport through single molecules: Scattering treatment using density functional and green function theories [J].

Derosa, PA ;

Seminario, JM .

JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (02) :471-481

[5]

Frisch M.J., 2016, Gaussian 16 Revision C. 01. 2016, V16, P01

[6]

HAY PJ, 1985, J CHEM PHYS, V82, P299, DOI [10.1063/1.448800, 10.1063/1.448799]

[7] Electronics using hybrid-molecular and mono-molecular devices [J].

Joachim, C ;

Gimzewski, JK ;

Aviram, A .

NATURE, 2000, 408 (6812) :541-548

[8] Bonding more atoms together for a single molecule computer [J].

Joachim, C .

NANOTECHNOLOGY, 2002, 13 (02) :R1-R7

[9]

KWOK KS, 2002, MATER TODAY, V5, P28, DOI DOI 10.1016/S1369-7021(02)05227-6

[10] Accurate and simple analytic representation of the electron-gas correlation energy (vol 45, 13244, 1992) [J].

Perdew, John P. ;

Wang, Yue .

PHYSICAL REVIEW B, 2018, 98 (07)

← 1 2 3 →