Theoretical and experimental X-ray photoelectron spectroscopy investigation of ion-implanted Nafion

被引：35

作者：

Hoffmann, EA

Fekete, ZA

Korugic-Karasz, LS

Karasz, FE ^{[1
]}

Wilusz, E

机构：

[1] Univ Massachusetts, Dept Polymer Sci & Engn, Amherst, MA 01003 USA

[2] Univ Szeged, Dept Phys Chem, H-6701 Szeged, Hungary

[3] USA, Natick Soldier Ctr, Natick, MA 01760 USA

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2004年 / 42卷 / 03期

关键词：

semiempirical calculations; quantum chemistry; fluoropolymers; ESCA/XPS; theory;

D O I：

10.1002/pola.10878

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The membrane properties of a Nafion surface can be modified by ion implantation with N+ or F+. The results are presented of an X-ray photoelectron spectroscopy (XPS) study of implanted surfaces. For the interpretation of the XPS spectra, calculations using a semiempirical quantum chemical formalism (AM1) have been applied, in conjunction with a charge-potential model, to predict the C,, cote electron binding energies. (C) 2003 Wiley Periodicals, Inc.

引用

页码：551 / 556

页数：6

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