Electrosynthesis of p-methoxybenzaldehyde on graphite/Nafion membrane composite electrodes

被引：11

作者：

Jiang, JH ^{[1
]}

Wu, BL ^{[1
]}

Cha, CS ^{[1
]}

机构：

[1] Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China

来源：

ELECTROCHIMICA ACTA | 1998年 / 43卷 / 16-17期

基金：

中国国家自然科学基金;

关键词：

solid polymer electrolyte; graphite; p-methoxybenzaldehyde; electrosynthesis; composite electrode;

D O I：

10.1016/S0013-4686(97)10152-9

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The electro-oxidation of p-methoxytoluene (p-MT) at the graphite/Nafion composite electrodes was investigated, p-Methoxybenzaldehyde (p-MBA) and a small amount of p-methoxybenzoic acid (p-MBAc) are obtained through preparative electrolysis of p-MT. There is slightly higher current efficiency at the composite electrode employing a Ce3+-Nafion membrane than at that employing a H+-Nafion membrane at low current densities.The electrochemical oxidation of p-MT is mainly a four-electron oxidation process controlled by the diffusion of some species. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：2549 / 2552

页数：4

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