A neutral triangular supramolecule formed by Mo24+ units

被引:89
作者
Cotton, FA
Lin, C
Murillo, CA
机构
[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA
[2] Texas A&M Univ, Mol Struct & Bonding Lab, College Stn, TX 77842 USA
[3] Univ Costa Rica, Dept Chem, San Jose, Costa Rica
关键词
D O I
10.1021/ic000963z
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Reaction of [cis-Mo-2(DAniF)(2)(CH3CN)(4)](BF4)(2), DAniF = N,N'-di-p-anisylformamidinate, and ((Bu4N)-N-n)(2)(trans-1,4-cyclohexanedicarboxylate) gives the first neutral molecular triangle derived from quadruply bonded dimolybdenum units.
引用
收藏
页码:575 / +
页数:4
相关论文
共 35 条
  • [1] High-nuclearity metal-cyanide clusters:: Assembly of a Cr8Ni6(CN)24 cage with a face-centered cubic geometry
    Berseth, PA
    Sokol, JJ
    Shores, MP
    Heinrich, JL
    Long, JR
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (40) : 9655 - 9662
  • [2] Self assembly of a diphenanthrolinylpyrene-bridged CuI trimer
    Bonnefous, C
    Bellec, N
    Thummel, RP
    [J]. CHEMICAL COMMUNICATIONS, 1999, (13) : 1243 - 1244
  • [3] *BRUK AN INSTR DIV, 1997, SAINT V5 06 SOFTW CC
  • [4] *BRUK AN INSTR DIV, 1998, SMART V5 5 SOFTW CCD
  • [5] Compounds in which the Mo24+ unit is embraced by one, two or three formamidinate ligands together with acetonitrile ligands
    Chisholm, MH
    Cotton, FA
    Daniels, LM
    Folting, K
    Huffman, JC
    Iyer, SS
    Lin, C
    Macintosh, AM
    Murillo, CA
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (09): : 1387 - 1391
  • [6] Cotton F.A., 1993, MULTIPLE BONDS METAL
  • [7] Supramolecular structures based on dimetal units: simultaneous utilization of equatorial and axial connections
    Cotton, FA
    Lin, C
    Murillo, CA
    [J]. CHEMICAL COMMUNICATIONS, 2001, (01) : 11 - 12
  • [8] Square and triangular arrays based on Mo24+ and Rh24+ units
    Cotton, FA
    Daniels, LM
    Lin, C
    Murillo, CA
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (18) : 4538 - 4539
  • [9] Cotton FA, 1999, CHEM COMMUN, P841
  • [10] COTTON FA, IN PRESS INORG CHEM