1,1′-(pyridine-2,6-diyl)bis(3-benzyl-2,3-dihydro-1H-immidazol-2-ylidene), a new multidentate N-heterocyclic biscarbene and its silver(I) complex derivative

被引：70

作者：

Caballero, A ^{[1
]}

Díez-Barra, E ^{[1
]}

Jalón, FA ^{[1
]}

Merino, S ^{[1
]}

Tejeda, J ^{[1
]}

机构：

[1] Univ Castilla La Mancha, Fac Quim, Dept Quim Inorgan Organ & Bioquim, E-13071 Ciudad Real, Spain

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2001年 / 617卷 / 01期

关键词：

imidazol-2-ylidene; pyridine; silver;

D O I：

10.1016/S0022-328X(00)00715-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

1,1'-(Pyridine-2,6-diyl)bis(3-benzyl-2,3-dihydro-1H-imidazole-2-ylidene) (5) is a new polydentate N-heterocyclic biscarbene, stable at - 20 degreesC in THF solution and obtained by deprotonation of the corresponding bisimidazolium salt 4. Reaction of 5 with silver(I) triflate yields the silver(I) complex 7. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：395 / 398

页数：4

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