Preparation and characterisation of polyaniline electrode modified with diamino-methylbenzoate

被引:25
作者
Inzelt, G [1 ]
Csahók, E [1 ]
Kertész, V [1 ]
机构
[1] Eotvos Lorand Univ, Dept Phys Chem, H-1518 Budapest 112, Hungary
基金
匈牙利科学研究基金会;
关键词
polyaniline; 3,5-diamino methylbenzoate; modification; electrochemical quartz crystal microbalance; spectroelectrochemistry;
D O I
10.1016/S0013-4686(01)00691-0
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The modification of electrodeposited polyaniline film by subsequent electrodeposition of diamino-methylbenzoate leads to a new material of interesting electrochemical, electrical and spectroscopic properties. The electronically conductive parent polymer can be transformed into a redox polymer, however, the electrochemical behaviour, the colour and the conductivity of the polymer during the modification procedure can be easily regulated, therefore, the required properties can be finely tuned. The formation and the properties of the new polymeric films were studied by electrochemical microgravimetric and spectroelectrochemical techniques. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:3955 / 3962
页数:8
相关论文
共 39 条
[1]  
[Anonymous], ELEKTROKHIMIYA
[2]   ELECTROCHEMICAL PROPERTIES OF POLY-ORTHO-AMINOPHENOL MODIFIED ELECTRODES IN AQUEOUS ACID-SOLUTIONS [J].
BARBERO, C ;
SILBER, JJ ;
SERENO, L .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1990, 291 (1-2) :81-101
[3]   COMPARATIVE-STUDY OF THE ION-EXCHANGE AND ELECTROCHEMICAL PROPERTIES OF SULFONATED POLYANILINE (SPAN) AND POLYANILINE (PANI) [J].
BARBERO, C ;
MIRAS, MC ;
KOTZ, R ;
HAAS, O .
SYNTHETIC METALS, 1993, 55 (2-3) :1539-1544
[4]   Influence of the preparation conditions on the properties of electropolymerised polyaniline [J].
Brandl, V ;
Holze, R .
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1997, 101 (02) :251-256
[5]   ELECTROSYNTHESIS AND PROPERTIES OF RING-SUBSTITUTED POLYANILINES [J].
CATTARIN, S ;
DOUBOVA, L ;
MENGOLI, G ;
ZOTTI, G .
ELECTROCHIMICA ACTA, 1988, 33 (08) :1077-1084
[6]   In situ conductimetry study of post-deposition modified polyaniline film [J].
Csahók, E ;
Vieil, E ;
Inzelt, G .
SYNTHETIC METALS, 1999, 101 (1-3) :843-843
[7]  
CUSHMAN RJ, 1986, J ELECTROANAL CHEM, V291, P335
[8]   Electrochemical quartz crystal microbalance studies on the electropolymerization processes of ortho-phenylenediamine in sulfuric acid solutions [J].
Dai, HP ;
Wu, QH ;
Sun, SG ;
Shiu, KK .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1998, 456 (1-2) :47-59
[9]   ELECTROACTIVE POLYANILINE FILMS [J].
DIAZ, AF ;
LOGAN, JA .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1980, 111 (01) :111-114
[10]   Conductive polymer blends as electrochromic materials [J].
Gazotti, WA ;
Casalbore-Miceli, G ;
Mitzakoff, S ;
Geri, A ;
Gallazzi, MC ;
De Paoli, MA .
ELECTROCHIMICA ACTA, 1999, 44 (12) :1965-1971