Metal-free conversion of methane and cycloalkanes to amines and amides by employing a borylnitrene

被引：71

作者：

Bettinger, Holger F. ^{[1
]}

Filthaus, Matthias ^{[1
]}

Bornemann, Holger ^{[1
]}

Oppel, Iris M. ^{[2
]}

机构：

[1] Ruhr Univ Bochum, Lehrstuhl Organ Chem 2, D-44780 Bochum, Germany

[2] Ruhr Univ Bochum, Lehrstuhl Analyt Chem, D-44780 Bochum, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 25期

关键词：

C-H activation; hydrocarbons; matrix isolation; methane; nitrenes;

D O I：

10.1002/anie.200705936

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) C-H insertion: Borylnitrenes, which are generated in situ by photoylsis of azides, convert unactivated alkanes by intermolecular C-H insertion into aminoboranes (see scheme), which in turn can be reacted further to give amines or amides. The boryl group serves two purposes: it converts the nitrene into a highly reactive BN vinylidene analogue, and it is easily cleaved from the product. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4744 / 4747

页数：4

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