Neutral, cationic, and zwitterionic ruthenium(II) atom transfer radical addition catalysts supported by P,N-substituted indene or indenide ligands

被引：52

作者：

Lundgren, Rylan J. ^{[1
]}

Rankin, Matthew A. ^{[1
]}

McDonald, Robert ^{[2
]}

Stradiotto, Mark ^{[1
]}

机构：

[1] Dalhousie Univ, Dept Chem, Halifax, NS B3H 4J3, Canada

[2] Univ Alberta, Dept Chem, Xray Crystallog Lab, Edmonton, AB T6G 2G2, Canada

来源：

ORGANOMETALLICS | 2008年 / 27卷 / 02期

关键词：

D O I：

10.1021/om700914k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of Ru-based complexes supported by P,N-substituted indene or indenide ligands have been prepared and tested for activity in the atom transfer radical addition Of CCl4 to alkenes. The catalytic performance was found to be influenced by the charge and substitution pattern of the P,N ligand and other coligands, as well as the nature of the counteranion, with the best of these catalysts being effective at low catalyst loadings and under mild conditions.

引用

页码：254 / 258

页数：5

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