Wet hydrodechlorination of p-chlorophenol using Pd supported on an activated carbon cloth

被引：78

作者：

Shindler, Y ^{[1
]}

Matatov-Meytal, Y ^{[1
]}

Sheintuch, M ^{[1
]}

机构：

[1] Technion Israel Inst Technol, Wolfson Dept Chem Engn, IL-32000 Haifa, Israel

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2001年 / 40卷 / 15期

关键词：

D O I：

10.1021/ie001019d

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The use of activated carbon cloths as supports for Pd catalyst has been investigated in a hydrodechlorination process. Using p-chlorophenol (CP) as a model compound, the influence of the catalyst preparation procedure and Pd content have been studied at 30-85 degreesC, showing good activity and selectivity. Kinetic analysis of these diffusion-independent results showed the reaction to be first-order with respect to each reactant concentration (CP and hydrogen). Analysis of diffusion and reaction shows that diffusion resistance will be significant in granules larger than 100 mum. Several simulations of adsorption, diffusion, and reaction are presented showing the effect of pellet size, of hydrogen pressure, and of adsorbent loading.

引用

页码：3301 / 3308

页数：8

共 20 条

[1]

AUER A, 1999, CARBON, V36, P159

[2] EXHAUSTIVE LIQUID-PHASE CATALYTIC HYDRODEHALOGENATION OF CHLOROBENZENES [J].

BALKO, EN ;

PRZYBYLSKI, E ;

VONTRENTINI, F .

APPLIED CATALYSIS B-ENVIRONMENTAL, 1993, 2 (01) :1-8

[3] FORMATION OF POLYCHLORINATED DIBENZOFURANS (PCDFS) AND DIBENZO-PARA-DIOXINS (PCDDS) FROM THE PYROLYSIS OF CHLOROBENZENES [J].

BUSER, HR .

CHEMOSPHERE, 1979, 8 (06) :415-424

[4]

CONVERTI A, 1994, J HAZARD MATER, V24, P127

[5] Hydrodechlorination and hydrodearomatisation of monoaromatic chlorophenols into cyclohexanol on Ru/C catalysts applied to water depollution: influence of the basic solvent and kinetics of the reactions [J].

Felis, V ;

De Bellefon, C ;

Fouilloux, P ;

Schweich, D .

APPLIED CATALYSIS B-ENVIRONMENTAL, 1999, 20 (02) :91-100

[6]

GALVAGNO S, 1993, STUD SURF SCI CATAL, V78, P163

[7] CATALYTIC HYDRODECHLORINATION OF CHLOROPHENOLS [J].

HOKE, JB ;

GRAMICCIONI, GA ;

BALKO, EN .

APPLIED CATALYSIS B-ENVIRONMENTAL, 1992, 1 (04) :285-296

[8] The shape-selectivity of activated carbon fibers as a palladium catalyst support [J].

Jin, H ;

Park, SE ;

Lee, JM ;

Ryu, SK .

CARBON, 1996, 34 (03) :429-431

[9]

KHOOBIAR S, 1987, CATALYST SUPPORTS SU, P201

[10] DIRECT CATALYTIC HYDRODECHLORINATION OF TOXIC ORGANICS IN WASTE-WATER [J].

KOVENKLIOGLU, S ;

CAO, ZH ;

SHAH, D ;

FARRAUTO, RJ ;

BALKO, EN .

AICHE JOURNAL, 1992, 38 (07) :1003-1012

← 1 2 →