Synthesis and Identification of Metastable Compounds: Black ArsenicuScience or Fiction?

被引：102

作者：

Osters, Oliver ^{[1
]}

Nilges, Tom ^{[1
]}

Bachhuber, Frederik ^{[2
]}

Pielnhofer, Florian ^{[2
]}

Weihrich, Richard ^{[2
]}

Schoeneich, Michael ^{[3
,4
]}

Schmidt, Peer ^{[3
,4
]}

机构：

[1] Tech Univ Munich, Dept Chem, D-85737 Garching, Germany

[2] Univ Regensburg, Inst Anorgan Chem, D-93040 Regensburg, Germany

[3] Hsch Lausitz FH, Fak Nat Wissensch Anorgan Festkorper & Mat 2, D-01968 Senftenberg, Germany

[4] Tech Univ Dresden, Inst Anorgan Chem, D-01062 Dresden, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 12期

关键词：

arsenic; metastable phases; phase formation; phosphorus; solid-state structures; PHOSPHORUS; PREDICTION; SYSTEMS;

D O I：

10.1002/anie.201106479

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Back in black: All metastable and stable phases can be identified for the solid solution arsenic/phosphorus by a combination of quantum-chemical calculations and investigations of the phase formation. Reaction paths for phase formations and transitions in situ were also evaluated. The results show that orthorhombic black arsenic (o-As) is metastable in pure form and has only been previously obtained by stabilizing impurities. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：2994 / 2997

页数：4

共 40 条

[1]

[Anonymous], ANGEW CHEM

[2]

[Anonymous], 2010, ANGEW CHEM, V122, P5370

[3]

[Anonymous], WIN XPOW VERS 2 08

[4]

[Anonymous], XRED VERS 1 36 X SHA

[5]

Barin I., 1997, Thermochemical data of pure substances

[6]

Binnewies M., 1999, Thermochemical data of elements and compounds

[7] COVALENT STRUCTURES OF PHOSPHORUS - A COMPREHENSIVE THEORETICAL-STUDY [J].

BOCKER, S ;

HASER, M .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1995, 621 (02) :258-286

[8]

Dovesi R., 2009, Crystal09 User's Manual

[9] Au2PbP2, Au2TlP2, and Au2HgP2:: Ternary gold polyphosphides with lead, thallium, and mercury in the oxidation state zero [J].

Eschen, M ;

Jeltschko, W .

JOURNAL OF SOLID STATE CHEMISTRY, 2002, 165 (02) :238-246

[10]

Hackert A, 1998, Z ANORG ALLG CHEM, V624, P74, DOI 10.1002/(SICI)1521-3749(199801)624:1<74::AID-ZAAC74>3.0.CO

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