Synthesis and structure of a tin(II) phosphatooxalate, Sn2(PO4)[C2O4]0.5 containing one-dimensional tin phosphate chains

被引：46

作者：

Natarajan, S ^{[1
]}

机构：

[1] Jawaharlal Nehru Ctr Adv Sci Res, Chem & Phys Mat Unit, Bangalore 560064, Karnataka, India

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1998年 / 139卷 / 01期

关键词：

D O I：

10.1006/jssc.1998.7774

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and structure of a nem tin(HT) phosphato-oxalate, Sn-2(PO4)[C2O4](0.5), containing one-dimensional tin phosphate chains are presented. The structure comprises a network of pyramidal SnO3, truncated square, pyramidal SnO4, and tetrahedral PO4 moieties which gives rise to one-dimensional tin phosphate chains separated by the oxalate groups. These linkages create Sn-O-Sn bonding in this structure. (C) 1998 Academic Press.

引用

页码：200 / 203

页数：4

共 19 条

[1] SYNTHESIS AND STRUCTURE OF A NOVEL MICROPOROUS GALLOPHOSPHATE, NA3GA5(PO4)(4)O-2(OH)(2)CENTER-DOT-2H(2)O [J].

ATTFIELD, MP ;

MORRIS, RE ;

GUTIERREZPUEBLA, E ;

MONGEBRAVO, A ;

CHEETHAM, AK .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (08) :843-844

[2] STRUCTURAL FEATURES OF ALUMINOPHOSPHATE MATERIALS WITH AI/P=1 [J].

BENNETT, JM ;

DYTRYCH, WJ ;

PLUTH, JJ ;

RICHARDSON, JW ;

SMITH, JV .

ZEOLITES, 1986, 6 (05) :349-&

[3] WEIGHTING SCHEME FOR LEAST-SQUARES STRUCTURE REFINEMENT [J].

CARRUTHERS, JR ;

WATKIN, DJ .

ACTA CRYSTALLOGRAPHICA SECTION A, 1979, 35 (JUL) :698-699

[4] NEW VISTAS IN ZEOLITE AND MOLECULAR-SIEVE CATALYSIS [J].

DAVIS, ME .

ACCOUNTS OF CHEMICAL RESEARCH, 1993, 26 (03) :111-115

[5]

JORDAN TH, 1980, INORG CHEM, V19, P2251

[6] CRYSTAL-STRUCTURE OF ANHYDROUS STANNOUS PHOSPHATE, SN3(PO4)2 [J].

MATHEW, M ;

SCHROEDER, LW ;

JORDAN, TH .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1977, 33 (JUN15) :1812-1816

[7] [H3N(CH2)(2)NH3](0.5)(2+)[Sn4P3O12](-): An open-framework Tin(II) phosphate [J].

Natarajan, S ;

Attfield, MP ;

Cheetham, AK .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (09) :978-980

[8]

NATARAJAN S, 1996, J CHEM SOC CHEM COMM, P1415

[9]

NATARAJAN S, 1997, J CHEM SOC CHEM COMM, P1089

[10]

NATARAJAN S, 1998, IN PRESS J SOLID STA

← 1 2 →