Design of conducting redox polymers: A polythiophene-Ru(bipy)(3)(n)circle plus hybrid material

被引：149

作者：

Zhu, SS ^{[1
]}

Swager, TM ^{[1
]}

机构：

[1] UNIV PENN,DEPT CHEM,PHILADELPHIA,PA 19104

来源：

ADVANCED MATERIALS | 1996年 / 8卷 / 06期

关键词：

D O I：

10.1002/adma.19960080609

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Communication: The thiophene-substituted Ru(L)(3)(2(+)) complex shown in the Figure was synthesized and found to undergo polymerization when electrochemically oxidized. The electrochemical characteristics of the resultant polythiophene-Ru(L)(3)(n(+)) hybrid material were found to be a composite of those displayed by isolated Ru centers and the polymer prepared from the metal-free ligand. This represents a promising approach to novel redox conductors.

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页码：497 / &

页数：5

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