(trans-1,2,2,3,4,4-Hexa-tert-butyl-1,3-cyclotetrasilanediyl) dipotassium:: Supramolecular structure of the silylpotassium-benzene complex

被引：14

作者：

Kyushin, S ^{[1
]}

Kawai, H

Matsumoto, H

机构：

[1] Gunma Univ, Grad Sch Engn, Dept Nano Mat Syst, Kiryu, Gumma 3768515, Japan

[2] Japan Sci & Technol Corp, Core Res Evolut Sci & Technol, Kawaguchi, Saitama 3320012, Japan

来源：

ORGANOMETALLICS | 2004年 / 23卷 / 03期

关键词：

D O I：

10.1021/om030397q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

(trans- 1,2,2,3,4,4-Hexa-tert-butyl- 1,3-cyclotet-rasilanediyl)dipotassium (3) was synthesized by the reduction of trans- 1,3-dibromo-1,2,2,3,4,4-hexa-tert-bu-tylcyclotetrasilane (2) with potassium. The X-ray crystallographic analysis of the 3-benzene complex showed a novel supramolecular structure, in which 3 and benzene are stacked alternatively to form an infinite 1-D structure.

引用

页码：311 / 313

页数：3

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