PET/PA Nanocomposite Blends with Improved Gas Barrier Properties: Effect of Processing Conditions

被引:14
作者
Donadi, S. [1 ]
Modesti, M. [1 ]
Lorenzetti, A. [1 ]
Besco, S. [1 ]
机构
[1] Univ Padua, Dept Chem Proc Engn, I-35131 Padua, Italy
关键词
blends; processing; barrier; nanocomposites; POLYMER BLENDS; NYLON-6; FILMS;
D O I
10.1002/app.34397
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The aim of this research is to develop nanocomposite polyethylene terephthalate-polyamide blends (PET/MXD6 blends) with low oxygen permeability. Particular attention has been paid to the relation between barrier properties and the processing route adopted and therefore four different strategies were considered. Mechanical characterization shows that clay may effectively act as reinforcing filler in PET/MXD6 blends. Morphological characterization shows the strong effect of the processing strategy on clay dispersion and its distribution between the PET and polyamide phases. Barrier properties of PET/MXD6 nanocomposite blends are enhanced with respect to neat PET polymer as well as PET/MXD6 blends. The significant effect of processing techniques on barrier properties is also revealed. (C) 2011 Wiley Periodicals, Inc. J Appl PolymSci 122: 3290-3297, 2011
引用
收藏
页码:3290 / 3297
页数:8
相关论文
共 17 条
[1]   PA66/PA12/clay based nanocomposites: morphology and physical properties [J].
Besco, Stefano ;
Lorenzetti, Alessandra ;
Roso, Martina ;
Modesti, Michele .
POLYMERS FOR ADVANCED TECHNOLOGIES, 2011, 22 (12) :1563-1571
[2]   Oxygen Barrier Properties of Poly(ethylene terephthalate) Nanocomposite Films [J].
Frounchi, Masould ;
Dourbash, Ahreza .
MACROMOLECULAR MATERIALS AND ENGINEERING, 2009, 294 (01) :68-74
[3]   Nylon 6/Na-montmorillonite nanocomposites prepared by compounding Nylon 6 with Na-montmorillonite slurry [J].
Hasegawa, N ;
Okamoto, H ;
Kato, M ;
Usuki, A ;
Sato, N .
POLYMER, 2003, 44 (10) :2933-2937
[4]  
Hu Y., 2004, P 62 ANN TECHN C EXH, P1106
[5]   Effect of water sorption on oxygen-barrier properties of aromatic polyamides [J].
Hu, YS ;
Mehta, S ;
Schiraldi, DA ;
Hiltner, A ;
Baer, E .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2005, 43 (11) :1365-1381
[6]   Review article: Polymer-matrix nanocomposites, processing, manufacturing, and application: An overview [J].
Hussain, Farzana ;
Hojjati, Mehdi ;
Okamoto, Masami ;
Gorga, Russell E. .
JOURNAL OF COMPOSITE MATERIALS, 2006, 40 (17) :1511-1575
[7]  
Manias E., 2007, J POLYM PREPR, V138
[8]   Transparency of polymer blends [J].
Maruhashi, Y ;
Iida, S .
POLYMER ENGINEERING AND SCIENCE, 2001, 41 (11) :1987-1995
[9]   ABS/clay nanocomposites obtained by a solution technique: Influence of clay organic modifiers [J].
Modesti, M. ;
Besco, S. ;
Lorenzetti, A. ;
Causin, V. ;
Marega, C. ;
Gilman, J. W. ;
Fox, D. M. ;
Trulove, P. C. ;
De Long, H. C. ;
Zammarano, M. .
POLYMER DEGRADATION AND STABILITY, 2007, 92 (12) :2206-2213
[10]   Improvement in gas permeability of biaxially stretched PET films blended with high barrier polymers: The role of chemistry and processing conditions [J].
Ozen, Ilhan ;
Bozoklu, Guelay ;
Dalgicdir, Cahit ;
Yucel, Orcun ;
Unsal, Emre ;
Cakmak, Muekerrem ;
Menceloglu, Yusuf Ziya .
EUROPEAN POLYMER JOURNAL, 2010, 46 (02) :226-237