A new ruthenium-catalyzed cleavage of a carbon-carbon triple bond: Efficient transformation of ethynyl alcohol into alkene and carbon monoxide

被引：115

作者：

Datta, S ^{[1
]}

Chang, CL ^{[1
]}

Yeh, KL ^{[1
]}

Liu, RS ^{[1
]}

机构：

[1] Natl Tsing Hua Univ, Dept Chem, Hsinchu 30043, Taiwan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 31期

关键词：

D O I：

10.1021/ja036246w

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report a new and efficient ruthenium-catalyzed reaction that transforms ethynyl alcohol into alkene and carbon monoxide. The most efficient catalysts are TpRu(PPh3)(CH3CN)2PF6 (10 mol %) and lithium triflate (20 mol %). The mechanism of this reaction was elucidated using an isotope-labeling experiment. Copyright © 2003 American Chemical Society.

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页码：9294 / 9295

页数：2

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