Triple-decker main group cations

被引：46

作者：

Cowley, AH ^{[1
]}

Macdonald, CLB ^{[1
]}

Silverman, JS ^{[1
]}

Gorden, JD ^{[1
]}

Voigt, A ^{[1
]}

机构：

[1] Univ Texas, Dept Chem & Biochem, Austin, TX 78712 USA

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 02期

关键词：

D O I：

10.1039/b005425i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The syntheses of the first main group triple-decker cations are described, namely, [(eta (5)-C5Me5)Sn(mu-eta (5)-C5Me5)Sn(eta (5)-C5Me5)][Ga(C6F5)(4)] and [(eta (6)-C7H8)In(mu-eta (5)-C5Me5)In(eta (6)-C7H8)][(C6F5)(3)BO(H)B(C6F5)(3)], both of which have been characterized by X-ray crystallography; the former was prepared by the reaction of Sn(eta (5)-C5Me5)(2) with Ga(C6F5)(3), while the latter was prepared by treatment of [In(eta (5)-C5Me5)](6) with an equimolar mixture of B(C6F5)(3) and H2O .B(C6F5)(3).

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页码：175 / 176

页数：2

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