Enantioselective syntheses of decursinol angelate and decursin

被引：33

作者：

Lim, J

Kim, IH

Kim, HH

Ahn, KS

Han, H ^{[1
]}

机构：

[1] Korea Univ, Dept Chem, Seoul 136701, South Korea

[2] Korea Univ, Grad Sch Biotechnol, Seoul 136701, South Korea

[3] Korea Res Inst Biosci & Biotechnol, Taejon 305333, South Korea

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 24期

关键词：

decursinol angelate; decursin; decursinol; catalytic asymmetric epoxidation; protein kinase C;

D O I：

10.1016/S0040-4039(01)00642-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The practical enantioselective syntheses of decursinol angelate and decursin were achieved in eight steps from resorcinol. The stereochemistry was addressed using the catalytic asymmetric epoxidation of 7-acetoxy-2,2-dimethylchromene by chiral (salen)Mn complexes as the key step. (C) 2001 Elsevier Science Ltd. All rights reserved.

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页码：4001 / 4003

页数：3

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