Unusual transformation of N-arylbenzohydroxamic acids mediated by osmium.: Formation of organometallic complexes of osmium(III)

被引:22
作者
Das, A
Basuli, F
Falvello, LR
Bhattacharya, S [1 ]
机构
[1] Jadavpur Univ, Dept Chem, Inorgan Chem Sect, Kolkata 700032, W Bengal, India
[2] Univ Zaragoza, Fac Sci, Dept Inorgan Chem, E-50009 Zaragoza, Spain
关键词
D O I
10.1021/ic0012569
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Unusual Transformation of N-Arylbenzohydroxamic Acids Mediated by Osmium. Formation of Organometallic Complexes of Osmium(III) The N-arylbenzohydroxamic acids (1) undergo unusual chemical transformation upon reaction with [Os(bpy)(2)Br-2] and afford a family of organometallic complexes of osmium(III) (2), where the transformed hydroxamic acids are coordinated to osmium as doubly deprotonated benzanilides.
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页码:4085 / +
页数:5
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