Synthesis of secondary allenylidene-molybdenum complexes with a ferrocenyl substituent from carbenium ions species stabilized by two organometallic moieties

被引：16

作者：

Capon, JF ^{[1
]}

LeBerreCosquer, N ^{[1
]}

Leblanc, B ^{[1
]}

Kergoat, R ^{[1
]}

机构：

[1] UNIV BRETAGNE OCCIDENTALE, CNRS, URA 322, EQUIPE CHIMN INORGAN MOLEC, F-29285 BREST, FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 508卷 / 1-2期

关键词：

iron; ferrocene; molybdenum; carbenium ions; allenylidene complexes;

D O I：

10.1016/0022-328X(95)05777-M

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The monoallenylidene complex [Cp(2)Mo(2)(CO)(4){mu-sigma:eta(2)-C=C-C(Fc)(H)}] (5) and the diallenylidene complex [{Cp(2)Mo(2)(CO)(4)(mu-sigma:eta(2)-C=C=C(H))}(2)Fc] (6) have been obtained from the corresponding monocarbenium ion [Cp(2)Mo(2)(CO)(4){mu-eta(2):eta(3)-HC=C-C(H)(Fc)}][BF4] (3) and the dicarbenium ion [{Cp(2)Mo(2)(CO)(4)(mu-eta(2):eta(3)-HC=C-C(H)}(2)Fc][(BF4)(2)] (4) respectively, and their spectroscopic data are determined.

引用

页码：31 / 37

页数：7

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