Design of highly active iron-based catalysts for atom transfer radical polymerization: Tridentate salicylaldiminato ligands affording near ideal Nernstian behavior

被引：139

作者：

O'Reilly, RK ^{[1
]}

Gibson, VC ^{[1
]}

White, AJP ^{[1
]}

Williams, DJ ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 28期

关键词：

D O I：

10.1021/ja035458q

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Iron(II) complexes bearing monoanionic tridentate salicyladiminato ligands are shown to be highly efficient catalysts for atom transfer radical polymerization (ATRP). Polymerization rates for styrene are among the highest reported for iron-mediated ATRP in nonpolar media, correlating well with E1/2 potentials and ΔEp values for the complexes. The rigidity of the tridentate ligands, combined with ample space around the metal center to accommodate a halogen atom, we believe to be an important factor in the efficient ATRP behavior of these systems. Copyright © 2003 American Chemical Society.

引用

页码：8450 / 8451

页数：2

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