Counter anion dependent symmetry of CuII-4-amino-1,2,4-triazole polymeric chains

被引:75
作者
Drabent, K [1 ]
Ciunik, Z [1 ]
机构
[1] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland
关键词
D O I
10.1039/b101936h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The symmetry changes and length of the symmetry independent part of [Cu(amtrz)(3)](n)(2+)(amtrz = 4-amino-1,2,4-triazole) polymeric chains driven by different anions in crystals with BF4 (-) (1), BF4- /SiF62-(2) and SiF62 (-)(3) have been studied by single crystal X-ray method.
引用
收藏
页码:1254 / 1255
页数:2
相关论文
共 11 条
[1]   Relation between electronic and spatial structure and spin-transition parameters in chain-like Fe(II) compounds [J].
Erenburg, SB ;
Bausk, NV ;
Lavrenova, LG ;
Varnek, VA ;
Mazalov, LN .
SOLID STATE IONICS, 1997, 101 :571-577
[2]   Synthesis and spin-crossover characteristics of polynuclear 4-(2′-hydroxy-ethyl)-1,2,4-triazole Fe(II) molecular materials [J].
Garcia, Y ;
van Koningsbruggen, PJ ;
Lapouyade, R ;
Rabardel, L ;
Kahn, O ;
Wieczorek, M ;
Bronisz, R ;
Ciunik, Z ;
Rudolf, MF .
COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE C-CHIMIE, 1998, 1 (08) :523-532
[3]   Synthesis, crystal structure, EXAFS, and magnetic properties of catena-poly[μ-tris(4-(2-hydroxyethyl)-1,2,4-triazole-N1,N2)copper(II)] diperchlorate trihydrate:: Relevance with the structure of the iron(II) 1,2,4-triazole spin transition molecular materials [J].
Garcia, Y ;
van Koningsbruggen, PJ ;
Bravic, G ;
Guionneau, P ;
Chasseau, D ;
Cascarano, GL ;
Moscovici, J ;
Lambert, K ;
Michalowicz, A ;
Kahn, O .
INORGANIC CHEMISTRY, 1997, 36 (27) :6357-6365
[4]   Pressure effect on a novel spin transition polymeric chain compound [J].
Garcia, Y ;
Ksenofontov, V ;
Levchenko, G ;
Gütlich, P .
JOURNAL OF MATERIALS CHEMISTRY, 2000, 10 (10) :2274-2276
[5]   THERMAL AND OPTICAL SWITCHING OF IRON(II) COMPLEXES [J].
GUTLICH, P ;
HAUSER, A ;
SPIERING, H .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1994, 33 (20) :2024-2054
[6]   Mononuclear, oligonuclear and polynuclear metal coordination compounds with 1,2,4-triazole derivatives as ligands [J].
Haasnoot, JG .
COORDINATION CHEMISTRY REVIEWS, 2000, 200 :131-185
[7]   EXAFS study on the spin-crossover system, [Fe(4-NH2trz)3](R-SO3)2 [J].
Kojima, N ;
Murakami, Y ;
Komatsu, T ;
Yokoyama, T .
SYNTHETIC METALS, 1999, 103 (1-3) :2154-2154
[8]  
Lavrenova L. G., 1998, KOORDINATS KHIM, V24, P403
[9]   Spin-transition behaviour in chains of FeII bridged by 4-substituted 1,2,4-triazoles carrying alkyl tails [J].
Roubeau, O ;
Gomez, JMA ;
Balskus, E ;
Kolnaar, JJA ;
Haasnoot, JG ;
Reedijk, J .
NEW JOURNAL OF CHEMISTRY, 2001, 25 (01) :144-150
[10]  
SINDITSKII VP, 1987, ZH NEORG KHIM+, V32, P1950