Judd-Ofelt theory in a new light on its (almost) 40th anniversary

被引:14
作者
Smentek, L
Wybourne, BG
Hess, BA
机构
[1] Nicholas Copernicus Univ, Dept Chem, Inst Phys, PL-87100 Torun, Poland
[2] Vanderbilt Univ, Dept Chem, Nashville, TN USA
关键词
phenomena; crystal and ligand fields; optical properties; spin-orbit effects;
D O I
10.1016/S0925-8388(01)01185-9
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The standard Judd-Ofelt theory of one photon electric dipole transitions in f(N) systems is discussed in the language of the one particle parametrization scheme. An overview of various physical mechanisms that contribute to the Judd-Ofelt intensity parameters is performed. The analysis of the morphology of these parameters is based on the static model of their original derivation, dynamic model, electron correlation third order approach, spin-orbit interaction influence, and an exotic perturbation caused by a specific mass shift. As a new aspect of the investigations on the physical nature of f <---->f transitions, a transformation of the Judd-Ofelt effective operators to their relativistic version is presented. In this approach the transition amplitude is expressed by the effective double tensor operators, acting within the 4f(N) shell, and effectively representing relativistic contributions. In particular, the relativistic form of the crystal field potential is employed, and in addition, the interactions through the crystal held potential within the spin-orbital space are included. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:645 / 648
页数:4
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