Novel palladium catalytic systems for organic transformations

被引：210

作者：

Nishimura, T ^{[1
]}

Uemura, S ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Sakyo Ku, Kyoto 6068501, Japan

来源：

SYNLETT | 2004年 / 02期

关键词：

oxidation; alcohol; palladium; C-C bond cleavage; asymmetric synthesis;

D O I：

10.1055/s-2004-815412

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This article summarizes the results of our recent studies on palladium catalytic systems for the oxidation of alcohols and alkenes using molecular oxygen or air together with several successful attempts to make the system recyclable from the viewpoint of 'green and sustainable chemistry'. In addition, palladium-catalyzed novel organic transformations of tert-alcohols (mainly cyclobutanols) and cyclobutanone oximes are also presented, where beta-carbon elimination involving C-C bond cleavage is a key step, together with some of their asymmetric versions.

引用

页码：201 / 216

页数：16

共 165 条

[1] Anastas P. T., 1998, GREEN CHEM THEORY PR
[2] [Anonymous], 1990, OXIDATIONS ORGANIC C
[3] [Anonymous], 1993, ORGANIC CHEM USING C
[4] Novel electron-rich bulky phosphine ligands facilitate the palladium-catalyzed preparation of diaryl ethers
Aranyos, A
Old, DW
Kiyomori, A
Wolfe, JP
Sadighi, JP
Buchwald, SL
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (18) : 4369 - 4378
[5] Augustine R.L., 1996, HETEROGENEOUS CATALY
[6] MULTI-STEP CATALYSIS FOR THE OXIDATION OF OLEFINS TO KETONES BY MOLECULAR-OXYGEN IN CHLORIDE FREE MEDIA
BACKVALL, JE
HOPKINS, RB
[J]. TETRAHEDRON LETTERS, 1988, 29 (23) : 2885 - 2888
[7] BACKVALL JE, 1990, J AM CHEM SOC, V112, P5160
[8] Palladium-catalyzed enantioselective oxidation of alcohols:: A dramatic rate acceleration by Cs2CO3/t-BuOH
Bagdanoff, JT
Ferreira, EM
Stoltz, BM
[J]. ORGANIC LETTERS, 2003, 5 (06) : 835 - 837
[9] Barthel-Rosa LP, 1999, COORDIN CHEM REV, V190, P587
[10] Selective oxidation of alcohols and aldehydes on metal catalysts
Besson, M
Gallezot, P
[J]. CATALYSIS TODAY, 2000, 57 (1-2) : 127 - 141

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