Copper-mediated cross-coupling of functionalized arylmagnesium reagents with functionalized alkyl and benzylic halides

被引:77
作者
Dohle, W [1 ]
Lindsay, DM [1 ]
Knochel, P [1 ]
机构
[1] Univ Munich, Inst Organ Chem, D-81377 Munich, Germany
关键词
D O I
10.1021/ol0163272
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
[GRAPHICS] Functionalized arylmagnesium halides, prepared via an iodine-magnesium exchange, undergo a smooth cross-coupling reaction with functionalized primary alkyl iodides and benzylic bromides in the presence of CuCN . 2LiCl, either in stoichiometric (with trimethyl phosphite as an additive) or catalytic quantities.
引用
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页码:2871 / 2873
页数:3
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