Spectroscopic and electronic properties of 1-azaallylmetal(I) (M = Cu or Au) complexes;: molecular structure of [{Au[μ-N(R)-C(Ph)CR2]}2] (R = SiMe3)

被引：11

作者：

Hitchcock, PB

Lappert, MF ^{[1
]}

Layh, M

Klein, A

机构：

[1] Univ Sussex, Chem Lab, Brighton BN1 9QJ, E Sussex, England

[2] Univ Stuttgart, Inst Anorgan Chem, D-70569 Stuttgart, Germany

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1999年 / 09期

关键词：

D O I：

10.1039/a900299e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [Li{N(R)C(Ph)CR2}(thf)] (R = SiMe3) with CuI or [AuCl(SMe2)] gave the stable metal complexes [{M[mu-N(R)C(Ph)CR2]}(2)] (M = Cu or Au) which were fully characterised by multinuclear NMR spectroscopy, mass spectrometry, microanalysis and for M = Au X-ray diffraction. Their spectroscopic and electrochemical properties are compared with the related copper complexes [{Cu[mu-N(R)C(Bu-t)C(H)R]}(2)], [Cu{N(R)C(Bu-t)=C(H)R}(PPh3)] and [Li(dme)(3)][Cu{N(R)C(Bu-t)=C(H)R}(2)].

引用

收藏

页码：1455 / 1459

页数：5

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