Electrodeposition of rhodium .2. Sulfate solutions

被引：38

作者：

Pletcher, D

Urbina, RI

机构：

[1] Department of Chemistry, The University

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1997年 / 421卷 / 1-2期

关键词：

rhodium; electrodeposition; sulfate;

D O I：

10.1016/S0022-0728(96)04845-0

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The electrodeposition of Rh from acidic sulfate media has been investigated. It is shown that, although nominally identical rhodium sulfate solutions prepared from different sources of Rh(III) have different speciations, their electrochemistry is the same and also simple. Good quality Rh electroplates may be obtained from these solutions. The origin of the adverse influence of chloride ion on the quality of electroplates is discussed.

引用

页码：145 / 151

页数：7

共 21 条

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ALIMARIN IP, 1970, J ANAL CHEM+, V25, P1688

[2]

[Anonymous], 1985, STANDARD POTENTIALS

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