Some theoretical and experimental limitations in the determination of surface free energy of siliceous solids

被引:27
作者
Bilinski, B [1 ]
Holysz, L [1 ]
机构
[1] Marie Curie Sklodowska Univ, Fac Chem, Dept Interfacial Phenomena, PL-20031 Lublin, Poland
关键词
silica gel; surface free energy; gas chromatography; thin column wicking;
D O I
10.1016/S0032-5910(98)00205-8
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The components of surface free energy of silica gel were calculated according to various theoretical approaches, and based on the data from different experimental methods (i.e., gas chromatography and thin column wicking). The results are compared, and widely discussed in terms of theoretical imperfections, accuracy of the liquid surface tension components data, as well as specific conditions (affecting the surface properties) implied by the used experimental method. Special attention was paid to adsorbed water layers. The differences in the results (especially those, dealing with donor-acceptor interactions) are discussed in terms of the mechanism of water vapour adsorption. The adsorbed water may provide an increase of electron-donor interactions of the surface. (C) 1999 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:120 / 126
页数:7
相关论文
共 49 条
[1]  
ADAMSON AW, 1990, PHYSICAL CHEM SURFAC
[2]  
[Anonymous], PROG COLLOID POLYM S
[3]  
[Anonymous], 1992, MODERN APPROACHES WE
[4]  
[Anonymous], 1995, COLLOID SURFACE B, DOI 10.1016/0927-7765
[5]   THE DETERMINATION OF THE DISPERSION AND POLAR FREE-SURFACE ENERGY OF QUARTZ BY THE ELUTION GAS-CHROMATOGRAPHY METHOD [J].
BILINSKI, B ;
CHIBOWSKI, E .
POWDER TECHNOLOGY, 1983, 35 (01) :39-45
[6]   THE INFLUENCE OF SURFACE DEHYDROXYLATION AND REHYDROXYLATION ON THE COMPONENTS OF SURFACE FREE-ENERGY OF SILICA-GELS [J].
BILINSKI, B .
POWDER TECHNOLOGY, 1994, 81 (03) :241-247
[7]   CORRELATION BETWEEN SURFACE FREE-ENERGY AND POROSITY OF CONTROLLED-POROSITY GLASSES [J].
BILINSKI, B ;
DAWIDOWICZ, AL .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1993, 70 (01) :61-67
[8]   Investigation of porous structure and surface properties of controlled porosity glasses [J].
Bilinski, B ;
Dawidowicz, AL .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1996, 118 (1-2) :149-160
[9]   THEORETICAL MOLECULAR-ORBITAL STUDY OF SILANOL WATER INTERACTIONS [J].
CHAKOUMAKOS, BC ;
GIBBS, GV .
JOURNAL OF PHYSICAL CHEMISTRY, 1986, 90 (06) :996-998
[10]   CONFRONTATION OF ENERGETIC CHANGES IN SULFUR N-ALKANE WATER AND SULFUR N-ALKANE VAPOR SYSTEMS [J].
CHIBOWSKI, E ;
BILINSKI, B ;
WAKSMUNDZKI, A ;
WOJCIK, W .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1982, 86 (02) :559-566