An organically templated layered vanadium oxide: Hydrothermal synthesis, single-crystal structure, and magnetic properties of (H3N(CH2)(3)NH3)[V4O10]

被引：107

作者：

Zhang, YP

OConnor, CJ

Clearfield, A

Haushalter, RC

机构：

[1] TEXAS A&M UNIV,DEPT CHEM,COLLEGE STN,TX 77843

[2] NEC RES INST,PRINCETON,NJ 08540

[3] UNIV NEW ORLEANS,DEPT CHEM,NEW ORLEANS,LA 70148

来源：

CHEMISTRY OF MATERIALS | 1996年 / 8卷 / 03期

关键词：

D O I：

10.1021/cm9503846

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Hydrothermal treatment of V2O5 with H2NCH2CH2CH2NH2 in H2O yields (H3N(CH2)(3)NH3)[V4O10], a layered mixed-valence vanadium oxide with protonated diaminopropane dications in the interlamellar space. The oxide layers are constructed from V5+O4 tetrahedra and pairs of edge-sharing V4+O5 square pyramids. This compound exhibits Curie-Weiss paramagnetism in the higher temperature region (T > 75 K) but undergoes a short-range antiferromagnetic ordering at 25 K.

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页码：595 / &

页数：4

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