Magnetic circular X-ray dichroism at pre-peak of Fe K-edge in ferrimagnetic Fe-oxides

被引:6
作者
Harada, I [1 ]
Suzuki, T [1 ]
Kotani, A [1 ]
机构
[1] UNIV TOKYO,INST SOLID STATE PHYS,MINATO KU,TOKYO 106,JAPAN
关键词
D O I
10.1016/S0368-2048(96)80072-7
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
We propose a mechanism of the magnetic circular X-ray dichroism (MCXD) at the pre-peak of the Fe K-edge in Fe-oxides. It is found that the hybridization between the 3d state and the 4p state of Fe ions at tetrahedral sites through the ligand 2p state is responsible for the weak electric-dipole absorption at the pre-peak while the spin-orbit interaction and the spin polarization in the 3d state play a crucial role in MCXD. The important effects of the configuration interaction as well as of the core hole are discussed in connection with the asymmetric dispersion-type MCXD observed in rare-earth iron garnets and magnetites.
引用
收藏
页码:251 / 254
页数:4
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