Structure and magnetic properties of a novel copper halide framework {[tBuNH3]2[Cu3(μ3-OH)(μ2-H2O)Cl7]}n synthesized via in situ templation

被引：32

作者：

Chivers, T ^{[1
]}

Fu, ZY

Thompson, LK

机构：

[1] Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada

[2] Mem Univ Newfoundland, Dept Chem, St John, NF A1B 3X7, Canada

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 18期

关键词：

D O I：

10.1039/b501040c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The use of the tris(alkylamido)phosphate OP[N(H)Bu-t](3) as an in situ source of the templating agent [(BuNH3)-Bu-t](+) produces the copper halide chain {[(BuNH3)-Bu-t](2)[Cu-3(mu(3)-OH)(mu(2)-H2O)Cl-7]}(n) (1) in a solvothermal process; the novel antiferromagnetically coupled trinuclear fragment Cu-3(OH)(H2O)Cl-7 is the building block in the polymeric anion in 1.

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页码：2339 / 2341

页数：3

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