Catalytic isomerization of 2-methyl-3-butenenitrile by nickel systems using bis-diphosphinoferrocene ligands:: Evidence for hemilability

被引：50

作者：

Acosta-Ramirez, Alberto

Munoz-Hernandez, Miguel

Jones, William D.

Garcia, Juventino J. ^{[1
]}

机构：

[1] Univ Nacl Autonoma Mexico, Fac Quim, Mexico City 04510, DF, Mexico

[2] Univ Autonoma Estado Morelos, Ctr Invest Quim, Morelos 62210, DF, Mexico

[3] Univ Rochester, Dept Chem, Rochester, NY 14627 USA

来源：

ORGANOMETALLICS | 2007年 / 26卷 / 24期

关键词：

D O I：

10.1021/om700928y

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The use of catalytic amounts of [Ni(COD)(2)] and a series of bis-diphosphinoferrocene ligands allows the catalytic isomerization of 2-methyl-3-butenenitrile to the linear 3-pentenenitrile, via allyl intermediates that display hemilability.

引用

页码：5766 / 5769

页数：4

共 19 条

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