Luminescent properties of Sm(III) ions in Ln2(WO4)3 entrapped in silica xerogel

Silica xerogel doped with Ln(2-x)Sm(x)(WO4)(3), where Ln = Gd(III) or La(III), were prepared by the sol-gel procedure. The parameter x in the formula was changed in the 0.02-2.0 range. Absorption and photoluminescence of a new kind of red light phosphors with emitting Sm3+ ions were studied at room temperature. In this type of luminescent material, prepared by the sol-gel method, samarium(III) ions exhibit enhanced luminescence emission owing to excitation energy transfer from WO42- groups to Sm3+ ions in the Ln(2-x)Sm(x)(WO4)(3) salt. The enhancement is particularly large for Gd2-xSmx(WO4)(3), where x = 0.1, and La2-xSmx(WO4)(3), x = 0.2, compounds entrapped in a silica xerogel. However, the La-Sm system exhibits higher emission intensity than the Gd-Sm material. The emission intensity of both the materials was additionally improved by removing O-H oscillators by the thermal treatment. (c) 2007 Elsevier B.V. All rights reserved.