Facile synthesis of functionalized nitroenamines .3. Aminolysis of 1-methyl-5-nitropyrimidin-2(1H)-one

被引：26

作者：

Nishiwaki, N ^{[1
]}

Tohda, Y ^{[1
]}

Ariga, M ^{[1
]}

机构：

[1] OSAKA KYOIKU UNIV, DEPT CHEM, OSAKA 582, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1996年 / 69卷 / 07期

关键词：

D O I：

10.1246/bcsj.69.1997

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The aminolysis of 1-methyl-5-nitropyrimidin-2(1H)-one furnished diimines of nitromalonaldehyde in good yields. One of the imino groups of the diimines was readily hydrolyzed on silica gel to give nitroenamines possessing a formyl group. These reagents behaved as the synthetic equivalent of unstable nitromalonaldehyde, affording azaheterocycles upon a treatment with hydrazines or diamines.

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页码：1997 / 2002

页数：6

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